Synthesis of PtCoNiRu/C nanoparticles by spray drying combined with reduction sintering for methanol electro-oxidation.

The controllable synthesis of carbon-supported platinum-based multicomponent alloys is important for the development and application of direct methanol fuel cells (DMFCs). In this paper, controllable synthesis of carbon-supported PtCoNiRu quaternary alloy is realized by spray drying and reduction sintering. The effects of reduction temperature on the size, morphology and catalytic properties of the metal nanoparticles were investigated. The electrochemical performance of the as-synthesized PtCoNiRu/C catalysts towards methanol electro-oxidation was studied using cyclic voltammetry (CV) and chronoamperometry. The results show that metal nanoparticles with uniform size and dispersity on the carbon surface can be obtained at a suitable sintering temperature, while the catalyst has a higher electrochemical active surface area (ECSA) and shows better catalytic activity and stability for methanol electro-oxidation. The method described in this study provides a new route for the manufacture of Pt alloy nanoparticles with higher catalytic activity and stability.

Experimental study on visual detection for fatigue of fixed-position staff.

Fatigue can lead to decreased work performance and poorer safety and health condition. Fatigue is ubiquitous in production and in life, while the research on it is mainly concentrated in the automotive driving, aircraft piloting and other fields, and it is insufficient to study on the fatigue of fixed-position staff. This paper puts forward a non-contact visual image method, which can monitor the extent of fatigue of fixed-position staff. Fatigue threshold used in judgment is obtained by processing the recorded data of visual images of the experimental subjects when fatiguing and by analyzing eye closure time, percentage of eyelid closure (PERCLOS) value, frequency and number of blinks. The results show that there is significant difference among the four indicators before and after experiment subjects undergo fatigue. The fatigue of experimental subjects is obvious when eye closure time is 3.5 s/min, PERCLOS value 6%, and blink frequency 0.4 times/s. This provides a reference for a wider range of detection of fatigue and a method for avoiding mistakes and accidents.